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Oil/Water Separation -
Demulsification
The need for new, efficient and potent demulsifiers to resolve difficult water-in-oil emulsions becomes more important.
Refinery Worker
 
 

Boost performance on formulation.
Improve oil demulsification process.

Dow Corning provides silicone technology for oil producers and service companies to improve their current crude oil demulsification process.

The Dow Corning® DMx line of silicone demulsifiers represents a range of different structures and molecular weights which have been proven effective in water/oil demulsification.

Silicone polyethers exhibit low surface tension (in some cases down to ? 21 dyn/cm compared to ? 30 dyn/cm for typical hydrocarbon surfactants in water) and low cohesive energy; they are surface active in both aqueous and nonaqueous media, and show inverse temperature solubility and cloud point. Some benefits that can be achieved are rapid water drop rate, better interface definition, better water quality, low temperature performance and overall improved cost efficiency for demulsification operations.

The effectiveness of silicone demulsifiers has been demonstrated over the years in the field, both as stand-alone additives and as performance boosters to organic-based formulations, in levels between 10 – 30 wt%, based on formulation active ingredients.

Key Advantages

  • Rapid water drop rate
  • Sharp interface definition
  • Improved water quality
  • Low temperature performance

Oilfields Conditions

  • ~70 producing wells coming into 4 parallel separators
  • Medium oil with some wax (controlled by pigging)
  • Average water cut ~60%
  • Residence time ~ 3 min
  • Temp: 50 - 60 °C
  • Pressure: 7-8 kg/cm2

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Field Trial Screen Result

Treatment detail

Final water content in oil

Final oil content in slop water

30 ppm glycol-based

3.0 - 7.2%

100 ppm

~8 ppm DM5

1.6 - 3.6%

< 25 ppm

18 ppm glycol-based +
1.5 ppm DM5 (Best)

~ 2% Optimized

< 50 ppm

23 ppm glycol-based +
2 ppm DM5

1% Demonstrated

< 50 ppm

Product Information

Products

Viscosity
cSt or mm2/s

Flash Point
Closed Cup °C

HLB Equivalent*

Dow Corning® DM1

1,750

71.5

6.6

Dow Corning® DM2

260

113

12.3

Dow Corning® DM3

280

83.3

6.6

Dow Corning® DM4

40

101

11.5

Dow Corning® DM5

310

67.2 9.2

Dow Corning® DM6

200

80 10.5
*HLB equivalent = (molecular weight of ethylene oxide/molecular weight of total polymer) x 20.
 

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